Publications

Arnold's Researcher ID: http://www.researcherid.com/rid/L-9112-2015

Brady GJ, Way AJ, Safron NS, Evensen HT, Gopalan P, Arnold MS
Quasi-ballistic carbon nanotube array transistors with current density exceeding Si and GaAs
 SCIENCE ADVANCES, 2 (9), e1601240 (2016)

Chang T-H*, Xiong S*, Jacobberger RM*, Mikael S, Suh HS, Liu C-C, Geng D, Wang X, Arnold MS, Ma Z , Nealey PF
Directed Self-Assembly of Block Copolymer Films on Atomically-Thin Graphene Chemical Patterns
 SCIENTIFIC REPORTS, 6, 31407 (2016) *Equal contributions.

Mashal A, Wieboldt D, Jinkins K, Arnold MS
Polarized Raman Spectroscopy of Aligned Semiconducting Single-Walled Carbon Nanotubes
 SPECTROSCOPY, 31 (6), pp 36–44 (2016)

Samad L, Bladow SM, Ding Q, Zhuo J, Jacobberger RM, Arnold MS, Jin S
Layer-Controlled Chemical Vapor Deposition Growth of MoS2 Vertical Heterostructures via van der Waals Epitaxy
 ACS NANO, 10 (7), pp 7039–7046 (2016)

Mehlenbacher R, McDonough T, Kearns N, Shea M, Joo Y, Gopalan P, Arnold MS, Zanni MT
Polarization Controlled 2D-WL Spectroscopy of Semiconducting Carbon Nanotube Thin Films
 JOURNAL OF PHYSICAL CHEMISTRY C 120 (30), pp 17069–17080 (2016)

McElhinny KM, Jacobberger RM, Zaug AJ, Arnold MS, Evans PG
Graphene-induced Ge (001) surface faceting
 SURFACE SCIENCE 647, 90–95 (2016)

Cao Y, Brady GJ, Gui H, Rutherglen C, Arnold MS, Zhou C
Radio-Frequency Transistors Using Aligned Polyfluorene-Sorted Semiconducting Carbon Nanotubes with ft and fmax Simultaneously Greater than 70 GHz
 ACS NANO, 10 (7), pp 6782–6790 (2016)

Mehlenbacher R, Wang J, Kearns N, Shea MJ, Flac J, McDonough R, Wu M-Y, Arnold MS, Zanni MT
Ultrafast Exciton Hopping Observed in Bare Semiconducting Carbon Nanotube Thin Films With 2DWL Spectroscopy
 JOURNAL OF PHYSICAL CHEMISTRY LETTERS 7 (11), pp 2024–2031 (2016)

Kiraly B, Mannix A, Jacobberger RJ, Fisher B, Arnold MS, Hersam MC, and Guisinger N
Sub-5 nm, Globally Aligned Graphene Nanoribbons on Ge(001)
 APPLIED PHYSICS LETTERS 108, 213101 (2016)

Davoody AH, Karimi F, Arnold MS, Knezevic I
Theory of Exciton Energy Transfer in Carbon Nanotube Composites
 JOURNAL OF PHYSICAL CHEMISTRY C 120 (30), pp 16354–16366 (2016)

Joo Y, Kim M, Kanimozhi C, Huang P, Wong BM, Singha Roy S, Arnold MS, Gopalan P
Effect of Dipolar Molecule Structure on the Mechanism of Graphene-Enhanced Raman Scattering
 JOURNAL OF PHYSICAL CHEMISTRY C 120 (25), pp 13815–13824 (2016)

Wei W, Samad L, Choi J, Joo Y, Way A, Arnold MS, Jin S, Gopalan P
Synthesis of Molybdenum Disulfide Nanowire Arrays Using Block Copolymer Template
 CHEMISTY OF MATERIALS 28 (11), pp 4017–4023 (2016)

Singha Roy S, Jacobberger RM, Wan C, Arnold MS
Controlling the Density of Pinhole Defects in Monolayer Graphene Synthesized via Chemical Vapor Deposition on Copper
 CARBON, 103 (2016)

Kiraly B, Jacobberger RM, Mannix AJ, Campbell GP, Bedzyk MJ, Arnold MS, Hersam MC, Guisinger NP
Electronic and Mechanical Properties of Graphene-Germanium Interfaces Grown by Chemical Vapor Deposition
 NANO LETTERS, 15 (11), pp 7414–7420 (2015)

Jacobberger RM, Kiraly B, Fortin-Deschenes M, Levesque PL, McElhinny KM, Brady GJ, Rojas Delgado R, Singha Roy S, Mannix A, Lagally MG, Evans PG, Desjardins P, Martel R, Hersam MC, Guisinger NP, Arnold MS
Direct Oriented Growth of Armchair Graphene Nanoribbons on Germanium
 NATURE COMMUNICATIONS, 6, 8006 (2015)

Choi JW, Kim M, Safron NS, Han E, Arnold MS, Gopalan P
A Facile Route for Fabricating Graphene Nanoribbon Array Transistors Using Graphoepitaxy of a Symmetric Block Copolymer
 SPIE PROCEEDINGS, 9428, 94280T, (2015)

Safron NS, Choi JW, Kim M, Shin N, Gopalan P, Arnold MS
Zigzag faceting and width refinement of graphene nanoribbons and nanoperforations via catalyzed edge-annealing on Cu(111)
 SOLID STATE COMMUNICATIONS, 224, pp 76–80 (2015)

Joo Y, Brady GJ, Shea MJ, Belιn Oviedo M, Kanimozhi C, Schmitt SK, Wong BM, Arnold MS, Gopalan P
Safron NS, Choi JW, Kim M, Shin N, Gopalan P, Arnold MS
Isolation of Pristine Electronics Grade Semiconducting Carbon Nanotubes by Switching the Rigidity of the Wrapping Polymer Backbone on Demand
 ACS NANO, 9 (10), pp 10203–10213 (2015)

Wu M-Y, Zhao J, Xu F, Chang T-H, Jacobberger RM, Ma Z, Arnold MS
Highly Stretchable Carbon Nanotube Transistors Enabled by Buckled Ion Gel Gate Dielectrics
 APPLIED PHYSICS LETTERS, 107, 053301 (2015)

Jacobberger RM, Machhi R, Wroblewski J, Taylor B, Gillian-Daniel AL, Arnold MS
Simple Graphene Synthesis via Chemical Vapor Deposition
 JOURNAL OF CHEMICAL EDUCATION, 92 (11), pp 1903–1907 (2015)

Li L, Chen X, Wang C-H, Cao J, Lee S, Tang A, Ahn C, Singha Roy S, Arnold MS, Wong H-SP
Vertical and Lateral Cu Transport through Graphene Layers
 ACS NANO, 9 (8), pp 8361-8367 (2015)

Mushenheim PC, Trivedi RR, Singha Roy S, Arnold MS, Weibel DB, Abbott NL
Effects of Confinement, Surface-Induced Orientations and Strain on Dynamical Behaviors of Bacteria in Thin Liquid Crystalline Films
 SOFT MATTER, 11 (34), pp 6821-6831 (2015)

Ferguson AJ, Dowgiallo A-M, Bindl DJ, Mistry KS, Reid OG, Kopidakis N, Arnold MS, Blackburn JL
Trap-limited carrier recombination in single-walled carbon nanotube heterojunctions with fullerene acceptor layers
 PHYSICAL REVIEW B, 91, 245311, (2015)

Mehlenbacher RD, McDonough TJ, Grechko M, Wu M-Y, Arnold MS, Zanni MT
Energy Transfer Pathways in Semiconducting Carbon Nanotubes Revealed using Two Dimensional White-Light Spectroscopy
 NATURE COMMUNICATIONS, 6, 6732 (2015)

Jacobberger RM, Levesque P, Xu F, Wu M-Y, Choubak S, Desjardins P, Martel R, Arnold MS
Tailoring the Growth Rate and Surface Facet for Synthesis of High-Quality Continuous Graphene Films from CH4 at 750 °C via Chemical Vapor Deposition
 JOURNAL OF PHYSICAL CHEMISTRY C, 119 (21), pp 11516-11523 (2015)

Singha Roy S, Safron NS, Wu M-Y, Arnold MS
Evolution, kinetics, energetics, and environmental factors of graphene degradation on silicon dioxide
 NANOSCALE, 7, pp 6093-6103 (2015)

Zhang L, Singha Roy S, Hamers RJ, Arnold MS, Andrew TL
Molecular Orientation-Dependent Interfacial Energetics and Built-in Voltage Tuned by a Template Graphene Monolayer
 JOURNAL OF PHYSICAL CHEMISTRY C, 119 (1), pp 45–54 (2015)

Yu Y, Li J, Geng D, Wang J, Zhang L, Andrew TL, Arnold MS, Wang X
Development of Lead Iodide Perovskite Solar Cells Using Three-Dimensional Titanium Dioxide Nanowire Architectures
 ACS NANO, 9 (1), pp 564–572 (2015)

Alley OJ, Wu M-Y, Johns GL, Dawidczyk TJ, Martνnez Hardigree JF, Markovic N, Arnold MS, Katz HE
Negative polarity of phenyl-C61 butyric acid methyl ester adjacent to donor macromolecule domains
 APPLIED PHYSICS LETTERS, 106, 033301 (2015)

Brady GJ, Joo Y, Wu M-Y, Shea MJ, Gopalan P, Arnold MS
Polyfluorene-Sorted, Carbon Nanotube Array Field-Effect Transistors with Increased Current Density and High On/Off Ratio
 ACS NANO, 8 (11), pp 11614–11621 (2014)

Shea MJ, Mehlenbacher RM, Zanni MT, Arnold MS
Experimental Measurement of the Binding Configuration and Coverage of Chirality-sorting Polyfluorenes on Carbon Nanotubes
 JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 5 (21), pp 3742–3749 (2014)

Brewer AS, Arnold MS
Field-effect measurements of mobility and carrier concentration of Cu2S colloidal quantum dot thin films after ligand exchange
 THIN SOLID FILMS, 567, pp 91-95 (2014)

Choi JW, Kim M, Safron NS, Arnold MS, Gopalan P
Transfer of Pre-Assembled Block Copolymer Thin Film to Nanopattern Unconventional Substrates
 ACS APPL. MATER. INTERFACES, 6 (12), pp 9442-9448 (2014)

Grechko M, Ye Y, Mehlenbacher R, McDonough T, Wu M-Y, Jacobberger R, Arnold M, Zanni, M
Diffusion Assisted Photoexcitation Transfer in Coupled Semiconducting Carbon Nanotube Thin Films
 ACS NANO, 8 (6), pp 5383–5394 (2014)

Yumin Y, Bindl DJ, Jacobberger RM, Wu M-Y, Singha Roy S, Arnold MS
Semiconducting Carbon Nanotube Aerogel Bulk Heterojunction Solar Cells
 SMALL, 10 (16), pp 3299-3306 (2014)

Brady G, Jacobberger R, Singha Roy S, Wall M, Arnold M
Raman Imaging as a Tool for Characterizing Carbon Nanomaterials
 AMERICAN LABORATORY, 46 (3), pp 12-15 (2014)

Joo Y, Brady GJ, Arnold MS, Gopalan P
Dose-controlled, Floating Evaporative Self-assembly and Alignment of Semiconducting Carbon Nanotubes from Organic Solvents
 LANGMUIR, 30 (12), pp 3460–3466 (2014)

Johnson PS, Huang C, Kim M, Safron NS, Arnold MS, Wong BM, Gopalan P, Himpsel FJ
Orientation of a Monolayer of Dipolar Molecules on Graphene from X-ray Absorption Spectroscopy
 LANGMUIR, 30 (9), pp 2559–2565 (2014)

Brady GJ, Joo Y, Singha Roy S, Gopalan P, Arnold MS
High performance transistors via aligned polyfluorene-sorted carbon nanotubes
 APPLIED PHYSICS LETTERS, 104, 083107 (2014)

Xu F, Wu M-Y, Safron NS, Singha Roy S, Jacobberger RM, Bindl DJ, Seo J-H, Chang T-H, Ma Z, Arnold MS
Highly Stretchable Carbon Nanotube Transistors with Ion Gel Gate Dielectrics
 NANO LETTERS, 4 (2), pp 682–686 (2014)

Huang C, Kim M, Wong B, Safron NS, Arnold MS; Gopalan P
Raman Enhancement of a Dipolar Molecule on Graphene
 JOURNAL OF PHYSICAL CHEMISTRY C, 118 (4), pp 2077–2084 (2014)

Safron NS, Arnold MS
Experimentally-Determined Intermediate Hydrocarbon Species Model of Atmospheric-Pressure Chemical Vapor Deposition of Graphene on Cu
 JOURNAL OF MATERIALS CHEMISTRY C 2, (14) pp 744-755 (2014)

Bindl DJ; Ferguson A; Wu M-Y; Kopidaki N; Blackburn J*; Arnold MS*
Free Carrier Generation and Recombination in Polymer Wrapped Semiconducting Carbon Nanotube Films and Heterojunctions
 JOURNAL OF PHYSICAL CHEMISTRY LETTERS 4 (21) pp 3550οΏ½3559 (2013)

Arnold MS, Blackburn JL, Crochet JJ, Doorn SK, Duque JG, Mohite A, and Telg H
Recent Developments in the Photophysics of Single-Walled Carbon Nanotubes for Their Use as Active and Passive Material Elements in Thin Film Photovoltaics
 PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 15 (36) pp 14896-14918 (2013)

Shea MJ, Arnold MS
1% Solar Cells Derived from Ultrathin Carbon Nanotube Photoabsorbing Films
 APPLIED PHYSICS LETTERS, 102, 243101 (2013)

Wu M-Y, Jacobberger RJ, Arnold MS
Design Length Scales for Carbon Nanotube Photoabsorber Based Photovoltaic Materials
 JOURNAL OF APPLIED PHYSICS, 113, 204504 (2013)

Mehlenbacher R, Wu M-Y, Grechko, M, Laaser J, Arnold MS, Zanni MT
Photoexcitation Dynamics of Coupled Semiconducting Carbon Nanotube Thin Films
 NANO LETTERS, 13 (4), pp 1495-1501 (2013)

Jacobberger RJ, Arnold MS
Graphene Growth Dynamics on Epitaxial Copper Thin Films
 CHEMSITRY OF MATERIALS, 25 (6), pp 871-877 (2013)

Singha Roy S, Arnold MS
Improving Graphene Diffusion Barriers via Stacking Multiple Layers and Grain Size Engineering
 ADVANCED FUNCTIONAL MATERIALS, 23 (29), pp 3638-3644 (2013)

Bindl DJ, Arnold MS
Efficient Exciton Relaxation and Charge Generation in Nearly Monochiral (7, 5) Carbon Nanotube / C60 Thin-Film Photovoltaics
 JOURNAL OF PHYSICAL CHEMISTRY C, 117 (5), pp 2390–2395 (2013)

Kim M, Safron NS, Han E, Arnold MS, Gopalan P
Electronic Transport and Raman Scattering in Size-Controlled Nanoperforated Graphene
 ACS NANO, 6 (11), pp 9846–9854 (2012)

Bindl DJ, Shea MJ, Arnold MS
Enhancing Extraction of Photogenerated Excitons from Semiconducting Carbon Nanotube Films as Photocurrent
 CHEMICAL PHYSICS, 413, pp 29-34 (2012)

Singha Roy S, Bindl DJ, Arnold MS
Templating Highly Crystalline Organic Semiconductors Using Atomic Membranes of Graphene at the Anode/Organic Interface
 JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 3 (7), pp 873–878 (2012)

Safron NS, Kim M, Gopalan P, Arnold MS
Barrier-Guided Growth of Micro- and Nano-Structured Graphene
 ADVANCED MATERIALS, 24 (8), pp 10441-1045 (2012)

Kim M, Safron NS, Huang C, Arnold MS, Gopalan P
Light-Driven Reversible Modulation of Doping in Graphene
 NANO LETTERS, 12 (1), pp 182–187 (2012)

Bindl DJ, Brewer AS, Arnold MS
Semiconducting Carbon Nanotube / Fullerene Blended Heterojunctions for Photovoltaic Near-Infrared Photon Harvesting
 NANO RESEARCH, 4 (11), pp 1174-1179 (2011)

Spalenka JW, Mannebach EM, Bindl DJ, Arnold MS , Evans PG
Spectral resolution of states relevant to photoinduced charge transfer in modified pentacene/ZnO field-effect transistors
 APPLIED PHYSICS LETTERS, 99: 193304 (2011)

Huang C, Wang R, Wong B, McGee D, Leonard F, Kim YJ, Johnson K, Arnold MS, Eriksson M, Gopalan P
Spectroscopic Properties of Nanotube-Chromophore Hybrids
 ACS NANO, 5 (10), pp 7767–7774 (2011)

Bindl DJ, Arnold MS
Semiconducting Carbon Nanotube Photovoltaic Photodetectors
 INTERNATIONAL JOURNAL OF HIGH SPEED ELECTRONICS AND SYSTEMS and the LESTER EASTMEN CONFERENCE PROCEEDINGS, 20, 3 (2011)

Safron NS, Arnold MS
Characterization of Conduction Mechanisms Relevant to Device Performance in Nanoperforated Graphene
 INTERNATIONAL JOURNAL OF HIGH SPEED ELECTRONICS AND SYSTEMS and the LESTER EASTMEN CONFERENCE PROCEEDINGS, 20, 3 (2011)

Bindl DJ, Wu M-Y, Prehn FC, Arnold MS
Efficiently Harvesting Excitons from Electronic Type-Controlled Semiconducting Carbon Nanotube Films
 NANO LETTERS, 11 (2), pp 455–460 (2011).

Safron NS, Brewer AS, Arnold MS
Semiconducting Two-Dimensional Graphene Nanoconstriction Arrays Fabricated Using Nanosphere Lithography
SMALL, 7 (4), pp 492–498 (2011).

Bindl DJ, Safron NS, Arnold MS
Dissociating Excitons Photogenerated in Semiconducting Carbon Nanotubes at Polymeric Photovoltaic Heterojunction Interfaces
 ACS NANO 4 (10), pp 5657–5664 (201).

Guisinger NP, Arnold MS
Beyond Silicon: Carbon-Based Nanotechnology
 MRS BULLETIN 35: 273-276 (2010)

Kim M*, Safron NS*, Han E, Arnold MS, Gopalan P
Fabrication and Characterization of Large-Area, Semiconducting Nanoperforated Graphene Materials
NANO LETTERS 10: 1125-1131 (2010)
* Equal contributions

Arnold MS, Zimmerman JD, Renshaw CK, Xu X, Lunt RR, Austin CM, Forrest SR
Broad Spectral Response Using Carbon Nanotube/Organic Semiconductor/C60 Photodetectors
NANO LETTERS 9: 3354-3358 SEPT 2009

Arnold MS, Suntivich J, Stupp SI, Hersam MC
Hydrodynamic Characterization of Surfactant Encapsulated Carbon Nanotubes Using an Analytical Ultracentrifuge
ACS NANO 2: 2291-2300 NOV 2008

Rajangam K, Arnold MS, Rocco MS, Stupp SI
Peptide Amphiphile Nanostructure-Heparin Interactions and their Relationship to Bioactivity
BIOMATERIALS 29: 3298-3305, 2008

Arnold MS, McGraw GJ, Lunt RR, Forrest SR
Direct Vapor Jet Printing of Three Color Segment Organic Light Emitting Diodes for White Light Illumination
APPLIED PHYSICS LETTERS FEB 4 2008

Arnold MS, Green AA, Hulvat JF, Stupp SI, Hersam MC
Sorting carbon nanotubes by electronic structure using density differentiation
NATURE NANOTECHNOLOGY 1 (1): 60-65 OCT 2006

Arnold MS, Stupp SI, Hersam MC
Optimizing the purification of biofunctionalized carbon nanotubes
PROCEEDINGS of ASME ICMSE, OCT 16, 2006

Zhu Z, Crochet J, Arnold MS, Hersam MC, Ulbricht H, Resasco DE, Hertel T
Pump-probe spectroscopy of exciton dynamics in (6,5) carbon nanotubes
JOURNAL OF PHYSICAL CHEMISTRY C 111 (10): 3831-3835 MAR 2007

Arnold MS, Guler MO, Hersam MC, Stupp SI
Encapsulation of carbon nanotubes by self-assembling peptide amphiphiles
LANGMUIR 21 (10): 4705-4709 MAY 2005

Arnold MS, Stupp SI, Hersam MC
Enrichment of single-walled carbon nanotubes by diameter in density gradients
NANO LETTERS 5 (4): 713-718 APR 2005

Stendahl JC, Zubarev ER, Arnold MS, Hersam MC, Sue H-J, Stupp SI
Structural modifications to polystyrene via self-assembling molecules
ADVANCED FUNCTIONAL MATERIALS 15 (3): 487-493 MAR 2005

Arnold MS, Lan S, Cruz SC, Sharping JE, Stupp SI, Kumar P, and Hersam MC
Optical absorption and transient photobleaching in solutions of surfactant encapsulated and DNA wrapped single-walled carbon nanotubes
PROCEEDINGS of the SPIE 5359: 376-386, 2004

Arnold MS, Sharping JE, Stupp SI, Kumar P, Hersam MC
Band gap photobleaching in isolated single-walled carbon nanotubes
NANO LETTERS 3 (11): 1549-1554 NOV 2003

Arnold MS, Stupp SI, Hersam MC
Tuning the optical properties of carbon nanotube solutions using amphiphilic self-assembly
PROCEEDINGS of the SPIE 4999: 238-248, 2003

Arnold MS, Avouris P, Pan ZW, Wang ZL
Field-effect transistors based on single semiconducting oxide nanobelts
JOURNAL OF PHYSICAL CHEMISTRY B 107 (3): 659-663 JAN 23 2003

Collins PC, Arnold MS, Avouris P
Engineering carbon nanotubes and nanotube circuits using electrical breakdown
SCIENCE 292 (5517): 706-709 APR 27 2001

Collins PG, Hersam M, Arnold M, Martel R, Avouris P
Current saturation and electrical breakdown in multiwalled carbon nanotubes
PHYSICAL REVIEW LETTERS 86 (14): 3128-3131 APR 2 2001

Patents

U.S. Patent No. 9394177, Nanostructured graphene with atomically-smooth edges

U.S. Patent No. 9368723, Dose-controlled, floating evaporative assembly of aligned carbon nanotubes for use in high performance field effect transistors

U.S. Patent No. 9327979, Methods for removing polymer coatings from single-walled carbon nanotubes

U.S. Patent No. 9287359, Oriented bottom-up growth of armchair graphene nanoribbons on germanium

U.S. Patent No. 9105480, Methods for the Fabrication of Graphene Nanoribbon Arrays Using Block Copolymer Lithography

U.S. Patent No. 8987707, Stretchable Transistors with Buckled Carbon Nanotube Films as Conducting Channels

U.S. Patent No. 8268180, Methods of fabricating large-area, semiconducting nanoperforated graphene materials

U.S. Patent No. 8110125, Separation of carbon nanotubes in density gradients

U.S. Patent No. 7982130, Polymer wrapped carbon nanotube near-infrared photovoltaic devices

U.S. Patent No. 6890654, Encapsulation of nanotubes via self-assembled nanostructures